For fixing pastel-drawings it is convenient to use the following medium: Pound 15 grams dry casein and 3 grams of borax together, and then shake the powder with constant stirring into 100 cubic centimetres of distilled water. After some hours a syrupy mass will have been formed. Dilute this with more water so as to make the liquid up to 750 cubic centimetres; then add 250 cubic centimetres of spirits of wine. After a time a white precipitate may form; pour off the somewhat opalescent liquid from this sediment. This fixative is to be sprayed on to the face of the pastel, care being taken [p. 319] to prevent the liquid from gathering in actual drops upon any part of the drawing. When the surface looks moist and shiny, it shows that it has been sufficiently dosed with the fixative. The more completely the ground is protected by the colour laid on, the less risk there is of the fixation affecting the appearance of the picture. If, however, the effect of the work has been obtained by a mere whiff of the powdery pigment, it is wiser to omit the fixing procedure, for the delicacy of such very fine layers of colour would thus be impaired. In any case, the artist who is concerned for the permanence of his work will always try to obtain his effects by building up as solid a layer of colour as possible.
Pastels, as already mentioned, containing no binding material, or next to none, drawings made with them are exempt from the drawbacks inseparable from the use of vehicles. Consequently there is no fear of the surface cracking, darkening, blooming, becoming brown, or otherwise altering. When we further consider that pastel-drawings, unlike water-colours, depend for their effect on the presence of a fairly solid layer of pigment, and that many colours which are unstable when employed in other methods of painting, have proved to be durable in pastel, we are bound to admit that this beautiful technique is not only simple in method but expressive in the effects which it commands; but is only capable of producing drawings which last better than most others, provided they are protected by glass, and are not exposed to damp.
Since the pastel crayons of the shops bear usually no indication of the pigments employed to colour them, and frequently contain unstable coal-tar dyes, special care must be taken to test their permanence when exposed to [p. 320] light. To do this it will suffice to expose to direct sunshine in bright weather one half of a strip on which clear tones of the set of coloured pastels which we wish to use have been spread and fixed. It is possible, if the sunshine be strong, to detect the more alterable pastels after a few days' exposure. For serious work the artist should use only such pastels as have stood the test. It is fortunate that, owing to the absence of any medium, chemical interaction between pastel-pigments when mixed together in the process of painting is virtually non-existent.
Details concerning the making at home of pastel-crayons will be bond in W. Ostwald's 'Letters to a Painter,' English edition, pp. 22-27. Here we need add only the following memoranda: Excellent pastel-grounds may be prepared by laying, on Bristol Board or Stout drawing paper, a thin and even coat of powdered pumice mixed with liquefied starch [see p. 95, document on Starch]. Or the same coat may be spread upon a surface of a fine fabric, such as tin calico, linen, or silk, previously secured to the board or paper by means of starch-paste. [p. 321]
Pastel or coloured chalk drawings frequently show a [p. 323] higher degree of preservation, so far as certain hues are concerned, than contemporary works executed in oil. One can easily account for the pure and fresh air of old pastel drawings, knowing that they have been carefully mounted and framed, and that there has been no oil or resin to yellow and darken the pigments. But how can the remarkable state of preservation in which the 'carnations' are found in so many examples be explained? Has the intimate commixture of chalk or of clay with crimson lake preserved the latter from the destructive action brought about by light? If there have been such a preservative action, has it been physical rather than chemical? Answers to such questions must be reserved until the chemistry of coloured pastels has been thoroughly studied. It should, however, be recollected that the white basis of coloured pastels is not always the same. In the eighteenth century it seems to have been invariably purified chalk, that is, 'whitening' or 'whiting,' which is essentially calcium carbonate. But, on examining lately a well-known make of French pastels, a considerable percentage of calcium sulphate was recognized, in addition to chalk. Further experiments seem to show that the colouring matter used is first ground up with a mixture of chalk and plaster-of-Paris, and that, in consequence, the subsequent addition of water causes the whole to set into a mass of just sufficient tenacity to hold together, though very soft and fragile. In this way the use of starch-water as a binding material is obviated. In other pastels pipe-clay or china-clay has been employed as the basis for the colouring matter.
[Church, Sir Arthur H., K.C.V.O., F.R.S., M.A., D.Sc., F.S.A., Sometime Professor of Chemistry in the Royal Academy of Arts in London. 4th Edition Revised and Enlarged. London: Seeley, Service & Co., Ltd., 1915. pp. 322-323]
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